CAI Shunyou.An approach to N,N-dimethyl-3-oxo-3-phenylpropanamide through copper catalyzed[J].Journal of Yanbian University,2016,42(02):115-118.
铜催化制备N,N-二甲基- 3-羰基- 3-苯基丙酰胺
- Title:
- An approach to N,N-dimethyl-3-oxo-3-phenylpropanamide through copper catalyzed
- Keywords:
- copper catalysis; oxidative coupling; β-ketoamide
- 分类号:
- O622
- 文献标志码:
- A
- 摘要:
- 在催化剂氧化亚铜、氢氧化钾和1大气压氧气及室温条件下,用苯甲醇与N,N-二甲基乙酰胺一步反应生成N,N-二甲基-3-羰基-3-苯基丙酰胺,并初步讨论了该反应机理.
- Abstract:
- N,N-dimethyl-3-oxo-3-phenylpropanamide is smoothly prepared through a copper-catalyzed the benzyl alcohol with N,N-dimethylacetamide in present of potassium hydroxide(KOH), under a balloon-oxygen atmosphere at room temperature. Additionally, a preliminary mechanistic investigation is suggested.
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备注/Memo
收稿日期: 2016-04-26 作者简介: 蔡顺有(1985—),男,博士,讲师,研究方向为有机合成.基金项目: 国家自然科学基金青年科学基金资助项目(21502086); 福建省自然科学青年创新项目(2015J05028); 闽南师范大学杰出青年科研人才培育计划项目(MJ14005)